Tag Archive: Chemistry Questions

O Level Chemistry: Question on Chemical Bonding

Chemical Bonding is one of the most important fundamental topics in O-Level Chemistry (and other equivalent Basic Chemistry syllabus). It is linked to many other topics in Chemistry. However, many students are not aware of it and take them very lightly.

Let’s check out a question that was emailed to me by one of the student that read this blog.

Hi

I just want to clarify whether the explanation is correct.

Q) Explain why graphite has a lower melting point than diamond. (1 mark).

The answer is “Graphite has fewer covalent bonds than Diamond.”

What about this answer:

“Graphite has weak van der wals forces between the layers. Lesser energy is required to overcome such forces. As a result, it has a lower melting point than diamond”.

Is this answer acceptable?

From my own understanding, diamond has 4 covalent bonds between the carbon atoms while graphite has 3 covalent bonds between the carbon atoms and weak van der wals forces. More energy is required to break the extra covalent bond in diamond than the weak van der wals forces between the layers of atoms in graphite.

Regards
Weijie

The suggested answer “Graphite has fewer covalent bonds than Diamond.” is INCORRECT and is one of the common mistakes made by students batch after batch every year. Not sure where he found this suggested answer though.

Weijie is correct in his own suggested answer. =)

Graphite  are made up of layers of hexagonal rings that are held together by weak intermolecular  van der Waals’ forces of attraction. Lesser energy is required to overcome such weak forces. As a result, it has a lower melting point than diamond which is made of carbon atoms that are covalently bonded strongly together to form an extensive 3-D network with tetrahedral arrrangement. A large amount of energy is required to break these strong covalent bonds.

Tips:

Covalent Bonds (an intramolecular bond) is much stronger than van der Waals’ forces (an intermolecular bond)

Remember to master this topic on Chemical Bonding if you want to excel in Chemistry. : )

O-Level Chemistry: Collection of Questions from my Chemistry Students

Note: For Singapore GCE O-Level Pure Chemistry Combine Science (Chemistry) students that are taking exams this coming week

Following are some quick questions that my O-Level Chemistry students asked me last two days as they revise their work and need to clarify some doubts before their exams.

I thought it would be great to share with all my readers (especially if you are one of those going for the exam also). Questions are posted in BLACK while my suggested answers / comments are posted in BLUE.

If you find the post useful to your friends, feel free to share the link with them. =)

Questions from Elizabeth:

Hi Mr Chua, I have 21 questions for you, could you kindly respond accordingly? Thanks ((:

1) What is the precision of measuring cylinder & pipette?

Measuring cylinder is to 1 cm3 accuracy.

Pipette normally is not used for measurement. Instead it is used to transfer specific volume of liquid/solution.
E.g 10 cm3, 25 cm3, 50 cm3, etc.

2) What exactly is calcium chloride?

It is an ionic compound / salt.

3) Is metal sulphate a salt?

Yes. Metal sulfate is a general term. So many examples you can easily think of are: Sodium sulfate, calcium sulfate, magnesium sulfate, etc.
They are all ionic compound / salt.

4) During O’s, for the test for sulphate, do I write:
-add nitric acid, then barium nitrate
OR
-add acidified barium nitrate?

Both can. And you will see either form in the questions in O-Levels. Adding nitric acid means to acidify barium nitrate solution.

5) To test for chlorine, do I use damp litmus paper OR damp blue litmus paper?

Given a choice, we would prefer to write damp blue litmus paper.
It turns from blue to red and then bleached.

6) What exactly happens when liquid freezes?

Liquid state changes to solid state.

Refer to Kinetic Particle Theory topic to understand how the ARRANGEMENT and MOVEMENT changes from L to S state.

7) What is the definition of ‘volatile’?

It refers to liquid that easily changes to gaseous state at room temperature.
E.g. Ethanol in perfume.

Sometimes, they apply it to solids that sublimes also. E.g. Solid iodine sublimes to become gaseous iodine at room temperature.

9) Does concentration affect cations?

Don’t understand this question.

10) For O’s,are these the only soluble hydroxides we need to know- Zinc, Aluminium & Potassium?

We talked about this before. I disagree with your answer above.
We usually remember Group I metal hydroxides are soluble in water (NaOH, KOH, LiOH)
as well as Ba(OH)2 for Group II metal hydroxides. Ca(OH)2 is sparingly soluble.

Zinc hydroxide and Alumnium hydroxide are INSOLUBLE! Refer to QA, test for Cations.

11) What does energy level on the energy profile diagram represent?

It shows 3 things.

1. Reactants higher or lower energy than Products
2. Enthalpy change is negative or positive
3. Presence of Activation Energy

12) In exo reactions, why do products have lower energy?

In EXO, enthalpy change is NEGATIVE.

Refer to the formula of:  Enthalpy Changes = HB-B + HB-M

Use the formula and reason out the thought process.

HB-B is endo (+ve) whereas HB-M is exo (-ve).

You will get it. Refer to textbook if you still dont. They give very good examples to understand.

13) Which is the definition of catalyst?

- Provide an alternative route for the reaction with lower activation energy?
- substance which speeds up the rate of reaction

Yes. Combine both sentence into one answer.

14) For the oxidation of ethanol, for the chemical equation, do I write 2[O] or O2?

If due to bacterial oxidation, we should write O2.

If used acidified potassium dichromate (VI) in lab, we normally write as 2[O].

Check textbook to re-affirm.

15) Is Group 1 hydroxides soluble?

Answer above.

16) For Group 1(Apart from SPA) salts, do I use titration or Excess method?

Theoretically, use TITRATION.

17) What are found ‘free’ in the ground?

The more common elements are Gold, Platinum and maybe silver.

18) For reduction by carbon, when do you know it will give Carbon Monoxide/ Carbon Dioxide?

I mentioned this before.

The equation required in your O-Level Pure Chemistry (code: 5072) is showing the use of carbon monoxide as the reducing agent.

Thus, the products from the reduction of iron (III) oxide in Blast Furnace should be MOLTEN IRON and CARBON DIOXIDE.

Forget about the carbon monoxide that your teacher told you it will happen for the prelim papers.

It is not in syllabus.

If O-Level it comes out, they will give you alot of clues if they want you to write the product as MOLTEN IRON and CARBON MONOXIDE.

19) Can Silver and Gold be reduced by Carbon and Hydrogen?

You meant Silver oxide? They can, but it is not necessary. You can simply heat it to get Silver metal.

Gold usually are found uncombined in the earth.

20) Do I write ‘Calcium Sillicate’ OR ‘slag’ for my answer during O level?

It is Calcium Silicate. You have made a spelling error.

Both should be fine if they asked for substance.

But if they ask for chemical name, then you should write Calcium Silicate.

If they asked for Chemical Formula, then you write it as CaSiO3.

21) When I add bromine to an AlkAne, do I say it decolourise slowly OR there is no observation?

I supposed you meant adding aqueous bromine, Br2(aq).

Alkanes are saturated hydrocarbons and will not react with aqueous bromine. Thus, no changes. Aqueous bromine remains reddish-brown.

Only alkenes will decolourised the reddish-brown aqueous bromine since they are unsaturated.

Thanks in advance for answering (:

Sent from my iPhone

Questions from Lay Teng:

Her questions are in fact from the Pass With Distinction book that i wrote for Shinglee Publisher.

1) When questions ask about compare & contrast, do we have to mention both Similarity & Differences?

Yes. You need to. Let’s say questions ask us to compare and contrast Evaporation & Boiling process, you are required to mention the similarity and differences.

Similarity: Both involves the change of state from liquid to gas of water.

Differences:

A. Boiling is fast while evaporation is slow

B. Boiling is throughout the whole liquid while evaporation only at the surface

C. Boiling occurs at 100 oC (BP of water) while evaporation occurs below the boiling point

2) How come the book state Caesium atom and Caesium ion has different number of shells? And why the atom and ion has the same mass?

The answers given in the book is correct.

Caesium atom has 6 electron shells. When it gives away one electron, it forms Caesium ion which has only 5 electron shells.

Mass number is only determined by the sub-atomic particles present in the nucleus. i.e. protons + neutrons.

Since when atom becomes ion, only electrons are transferred, the mass will stay the same.

O Level Chemistry: Question on Periodic Table & Group Trends

In the previous blog post, we have discussed on the Group Trends of the Halogens (Group VII elements).

Today, i shall discuss with you an exam-based multiple choice question (MCQ) that test you on your concepts on Group Trends.

Below is an exam-based question send in by one of Sec 3 (2011) O-Level Pure Chemistry student:

Question:

HELLO MR CHUA;
i have chem P2 on friday and i did my school’s past year paper. i asked my teacher this qn, but i don’t understand D:
the ans is D but i don’t understand why (:
Which is most likely to be the most stable compound?
A. NaCl
B. RbCl
C. NaF
D. RbF                             ( D )

Suggested Solution:
Before we start, you need to understand which topic they are testing you on. On the first look, it seemed to be question on Chemical Bonding topic.

But once you realised they asked you about “stability” of the compounds, you need to know they are in fact asking about the chemical reactivity of Group I and VII elements, and thus the stability of the ionic compound that is formed.

The most stable compound must be made up of the most reactive metal and the most reactive non-metal for an ionic compound.

Group I Trend: Reactivity increases down the Gp I i.e. Rb is more reactive than Na

Group VII Trend: Reactivity decreases down the Gp VII i.e. F is more reactive than Cl

As such, RbF (D) will be the most stable compound among the four choices.

Hope you are learning something useful here. Feel free to forward this blog post to your friends if you think they can benefit from it. Keep sharing =)

O Level Chemistry: Question on Chemical Bonding

Chemical Bonding is an important topic to learn for Chemistry. In fact, fundamentally, it is one of the most important topic that is related to other topics in O-Level Chemistry (and equivalents).

There are 3 types of Bondings:

  1. Ionic Bonding
  2. Covalent Bonding
  3. Metallic Bonding

Today, we will discuss a question on bonding that was sent  by a Sec 4 O-Level Chemistry student. I reckon that the question was taken from his school’s preliminary examination paper.

Now, first we need to recognise that the substance is a covalent compound, meaning only covalent bonding exists in the molecule.

To recap, the element that is involved in bonding can have maximum of only 8 valence electrons (exception: Hydrogen with maximum of 2 valence electrons) around itself after bonding.

The 8 electrons can be bonded and can also be unbonded.

Answer is (B) i.e. X = Nitrogen; Y = Silicon and Z = Hydrogen

Reasons as follows:

  • Nitrogen is in Group V –> has 5 valence electrons –> 3 electrons used for covalent bonding + 2 unbonded valence electrons
  • Silicon is in Group IV –> has 4 valence electrons –> all 4 electrons are used for covalent bonding
  • Hydrogen has only 1 valence electron –> electron is used for covalent bonding

Hope you are learning something useful in this post.

PS: If you think this is beneficial to your friend, feel free to forward them this website. =)

O Level Chemistry: Question on Preparation of Salts

This question is about Preparation of Salts that was sent to me by one of my Sec 4 Pure Chemistry student.

Before we take a look at the question, let’s recap that there are 3 main methods to prepare salts in the laboratory:

  1. Titration
  2. Acids + Excess Insoluble Substances
  3. Precipitation

If you need more information on Preparation of Salts, you can go to my earlier blogposts under archives.

Let’s take a look at the question.

Question:

A student was given two beakers, one containing an aqueous solution of sodium chloride and the other aqueous lead (II) nitrate. He was told to prepare lead (II) chloride using those reagents.

(i) What is the name of the method that he used to prepare the salt?

(ii) Name the other  product made, besides lead (II) chloride

(iii) Write an ionic equation for the preparation.

In the process of doing the experiment, he accidentally spilled some of the salt solutions. Since he could not obtain sufficient lead (II) chloride, he tried to prepare more lead (II) chloride by adding solid lead (II) carbonate to dilute hydrochloric acid. Effervescence was seen but the reaction stopped in a short while.

(iv) Why was there effervescence?

(v) Why was he unsuccessful in preparing lead (II) chloride from the process of adding dilute hydrochloric acid to lead (II) carbonate?

Go try it out and leave your answers (and workings) in the Comment Section below.

PS: Feel free to share this blogpost with your friends or classmates, if you think they will benefit from it

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Chemistry Phenomenon: Educational Trip to Northern Vietnam – Nov 2010


Youtube video: http://www.youtube.com/watch?v=rYt6phIXt9E

Hello everyone!

I reckoned some of you would have finished your major exams (GCE O-Levels, IP, IB and IGCSE). Congrats! It’s time for your to enjoy your holiday before you embark on the next stage of your academic and knowledge pursuance.

It has been a while since you last hear from me. We (Winners Education Group) just came back from our educational trip to Northern Vietnam (Hanoi City, Sapa and Halong Bay, etc) and we have learned alot about their:

  • Educational system for Primary, Secondary, High School and Universities
  • Educational levels as compared to other developed and developing nations
  • History and Literature
  • Language and Economy

And, of course – i saw several interesting Chemistry Phenomenon – Chemistry reactions and actions that are related to our everyday life!

Halong Bay – an UNESCO World Heritage Site has 2000+ limestone structures that are formed due to the wave and wind erosion of one huge island, over thousands and thousands of years.

Halong Bay - Unesco World Heritage

We also saw villagers selling home-made Corn Wine along the streets! This corn wine has 50% v/v alcohol (ethanol) content!

Tribal Lady selling Corn Wine

And apparently some villagers used it to power and run their cars and motorbikes! Chemistry students! Ready for actions?

Successful Completion of annual Score 100% MCQ Mastery Workshop 2010

Updates from O-Levels students that have taken the Pure Chemistry Paper 1 (MCQ) on 12th Nov 2010:

“Hi Sean. 7 questions from the Score 100% Chemistry MCQ Mastery Workshop” came out for Chemistry Paper 1!”
- Timothy Wang, ACS(Independent) 2010 [Text sms on 12th Nov]

“Thank you very much Mr Chua! Some same exact questions that you gave us in the wkshop came out in the exam!! I could also apply whatever you taught us throughout this year…Thanks a lot for your guidance, Mr Chua! =) ”
- Nanthini, St. Margaret School 2010 [Text sms on 12th Nov]

Score100MCQ_Overall

I am pleased to share with you the successful completion of the annual GCE O-Levels Pure Chemistry “Score 100% MCQ Mastery Workshop 2010″ on 6th November 2010.

A total of 62 GCE O-Levels students attended this awesome  annual event with the aim of helping them to score high for their Pure Chemistry Paper 1 (MCQ) Paper which has an overall weightage of 30%.

I am so proud of this group of students taking time off to attend this workshop. There is a say that “80% of the Success is about taking the necessary Actions” and you can certainly know that this group of students are serious in improving their overall Chemistry grades.

Score100MCQ_1

Score100MCQ_2

Score100MCQ_3

Now, i would like to wish every GCE O Levels Chemistry (Pure Chemistry and Combine Science Chemistry) students the best in their MCQ Paper. Remember to manage your time and shade your answers carefully.

PS: You can click the link below for a collections of Chemistry MCQ questions that were discussed in this chemistry blog.

>> http://www.simplechemconcepts.com/tag/chemistry-mcq/

PPS: Feel free to let anyone know about this if you think they can benefit from it.